摘要:据国外资料介绍,汽车制造工业中应用环氧树脂的部位极多,如环氧树脂制的粘接剂、玻璃钢、涂料等应用在汽车结构件的粘接,车架及车身涂料。环氧树脂在汽车制造工业中的应用国内报导不多,这方面的推广应用引人注目,通过对国外一些配方的介绍,以期引起重视。

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style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>汽车制造工业在我国发展的速度极快,据报导全国各种汽车制造厂、汽车改装厂、汽车修造厂每年生产出各类汽车总量达lang=EN-US>80style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>万辆。随着奥迪、大众、标致、五十令、夏利、依维柯等等先进汽车生产线的引进,使我国汽车制造工业有了进一步的发展。

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众所周知,汽车制造中涉及很多的材料,特别是为了提高汽车的性能,减轻车身重量,增加外表的美观,国外对汽车使用的材料进行了很多的研究,寻找出经济实用的非金属结构材料。如以粘接剂代替焊接,用玻璃钢板代替金属材料,用电泳漆、粉末涂料取代传统的漆料,因而使环氧树脂在汽车制造工业中的应用越来越广。

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资料中介绍了以糊状粘接剂代替焊接的经验,特别是顶盖、行李箱等部位外板和内板的粘接,以及车门、车身、车身折边的密封都使用了粘接剂。为此研究出一种汽车专用的具有起始强度高的环氧粘接剂,其组成如下:环氧树脂
lang=EN-US style=”mso-spacerun: yes”>    style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>新戊二醇二缩水甘油醚
  style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>双氰胺lang=EN-US style=”mso-spacerun: yes”>   style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>聚乙烯醇缩甲醛lang=EN-US style=”mso-spacerun: yes”>   style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>聚乙烯lang=EN-US style=”mso-spacerun: yes”>   style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>滑石粉lang=EN-US style=”mso-spacerun: yes”>  style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>染料。
style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>该粘接剂初始强度达lang=EN-US>450style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>磅lang=EN-US>/style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>英寸lang=EN-US>2style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>,最终强度可达lang=EN-US>2100style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>磅lang=EN-US>/style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>英寸lang=EN-US>2style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>。

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另一资料介绍了汽车内、外板折边粘接及密封用的环氧树脂粘接剂:环氧树脂、双氰胺、二甲基咪唑、丁苯橡胶、腈橡胶、碳黑、碳酸钙,制得了具有熔融粘度(
lang=EN-US>80style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>)lang=EN-US>200000CPstyle=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>的粘接剂。

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为了减轻车身重量,资料中介绍了多功能板形增强材料,该材料不仅重量轻,而且有抗震性的绝热性。它是由
lang=EN-US>PVCstyle=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>和环氧树脂混合而成,其中加入发泡剂及其它的添加剂,烘烤发泡及固化。它能使汽车造价降低lang=EN-US>40%style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>,重量减轻lang=EN-US>60%style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>。采用该材料的部位为车门板、车背板。在另一资料中介绍了车体用金属板增强材料,其组成如下:style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>环氧树脂lang=EN-US style=”mso-spacerun: yes”>  style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>双氰胺lang=EN-US style=”mso-spacerun: yes”>  style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>腈橡胶lang=EN-US style=”mso-spacerun: yes”>  style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>丁基橡胶lang=EN-US style=”mso-spacerun: yes”>  style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>粘土lang=EN-US style=”mso-spacerun: yes”>  style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>金属纤维lang=EN-US style=”mso-spacerun: yes”>  style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>三聚硅酸铝
将上述混合物压辊成
lang=EN-US>1.0mmstyle=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>板,复在lang=EN-US>0.3 mmstyle=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>钢板上起到增强作用。

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还有人对车用减震器进行了研究,提出了由环氧树脂制备减震器阻尼材料及减震涂料:环氧树脂、多元胺、酚醛树脂。

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我国汽车用粘接剂生产情况报导不多,而对车用涂料则十分重视,据不完全统计已有
20style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>多家厂引进了汽车涂料生产线,总吨位达每年lang=EN-US>3style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>万多吨,其中环氧树脂电泳漆、粉末涂料占了很大比例。

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随着车中装备的不断完善,如许多汽车上都不同程度地配上录音机、放像机、电视机、监视器、冷气机等,车用绝缘材料的量也随之增加,而这些制品绝缘材料大部分为环氧树脂组成。据国外资料介绍,每辆车约用
lang=EN-US>5style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>公斤环氧树脂制品,则我国汽车制造工业中每年需用环氧树脂制品达lang=EN-US>5style=”FONT-FAMILY: 宋体; mso-ascii-font-family: ‘Times New Roman’; mso-hansi-font-family: ‘Times New Roman'”>千吨左右,这是一个相当可观的数字,因此国产环氧树脂如何挤身于汽车制造工业这个大市场,已成为引人注目的事。